Investigation of the Potential of African Oil Bean Seed as a Feedstock for Biodiesel Production using Iron (Iii) Oxide
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Biodiesel which is the diesel fuel derived from renewable sources such as plant oils and animal fats, holds a significant potential as a sustainable alternative to conventional fossil fuels. However, the cost of its production has remained a major obstacle to the widespread production and commercialization of this globally established renewable alternative energy source. This study investigated the potential of African oil bean seed as a viable feedstock for biodiesel production using iron (iii) oxide as catalyst. In carrying out this research, oil was extracted from African oil bean seed by the Soxhlex solvent extraction method using N-hexane, and converted into biodiesel with Iron (iii) oxide as a catalyst through base-catalyzed transesterification process. The oil and biodiesel yields were found to be 38% and 92% respectively. The result of the biodiesel characterization through determination of its physicochemical properties revealed that the biodiesel has these values; viscosity (1.67mm2/s), specific gravity (0.898), density (0.9 g/cm2), saponification number (174.8 mg KOH/g), free fatty acid (0.5%), iodine value (17.56 gI2/100g), cloud point (10.2), pour point (9.5), flash point(223.5oC), cetane number (108.3), calorific value (47,4 MJ/kg). The values are within the acceptable range prescribed by ASTM D6751for biodiesel, except the high cetane number, cloud point, pour point, which can be reduced with appropriate additives. This biodiesel compared well with the hydrocarbon diesel fuel. Furthermore, the percentage oil and biodiesel yields were high, thereby confirming African oil bean seed and Iron (iii) oxide as a viable feedstock, and cheap catalyst respectively, for biodiesel production.
A. Demirbas, Biodiesel from vegetable oils via transesterification in supercritical methanol. Energy Conversion and Management, 49(1), 2008, pp.125-130.
Elia, M., Licursi, D., & Rossi, S. Life cycle assessment of biodiesel production from rapeseed oil. Journal of Cleaner Production, 52,2013, pp.182-191.
Kafarov, V., Advances in biodiesel production: processes and technologies. Boca Raton, FL: CRC Press, 2015.
Manohar, S., & Chandrasekhar, K., Biodiesel production from jatropha oil and its characterization. International Journal of Chemical Engineering and Applications, 3(4), 2012, pp. 259-263.
Meher, L. C., VidyaSagar, D., & Naik, S. N.,Technical aspects of biodiesel production by transesterification: a review. Renewable and Sustainable Energy Reviews, 10(3), 2006, pp. 248-268.
Biodiesel Production Via Acid Catalysis Retrieved online July 15, 2025. https://biodieseleducation.org
Wikipedia, Transesterification Retrieved online July 15, 2025. https://en.wikipedia.org
Kalayasiri P, Jayashoke N, Krisnangkura K (1996) Survey of seed oils for use as diesel fuels. J Am Oil Chem Soc 73:471–474
ARO SCIENTIFIC, Pour Point of Petroleum Products- A Brief Guide, 2024. Retrieved online, June 2024.
Foroutan R, Esmaeili H, Mousavi SM, Hashemi SA, Yegaaneh G. The physical properties of biodiesel-diesel fuel produced via transesterification process from different oil sources. Physical Chemistry Research. 2019;7(2):415-424. DOI: 10.22036/pcr.2019.173224
Okonkwo PA, Omenihu I. Production and characterization of biodiesel from mango seed oil (MSO). Nigerian Journal of Technology. 2021:598-607. DOI: 10.4314/ njt.40i4.6.2021, 598-607
Ajala A, Kanokwon N, Worapon K, Doonyapong W, Suttichai A. Effect of water content in waste cooking oil on biodiesel production via ester transesterification in a single reactive distillation. International Conference on Smart Materials Applications IOP Conf. Series: Materials Science and Engineering. 2019;559:012014. DOI: 10.1088/1757-899X/559/1/012014
Leung DYC, Xuan W, Leung MKH. A review on biodiesel production using catalyzed transesterification. Applied Energy. 87, 2010,pp.1083-1095
Macmanus C. Ndukwu and C.I Onyeoziri, African oil bean seed as feedstock for bio-oil and biodiesel production and on the effects of thermal pre-treatment on the quality of the bio-oil. Biomass Conversion and Biorefinery, 2020 Doi:10.1007/s13399-020-00754-6
Shuman Guo, Zhenzhong Yang, and Yuguo Gao, Effect of Adding Biodiesel to Diesel on the Physical and Chemical Properties and Engine Performance of Fuel Blends, Journal of Biobased Materials and Bioenergy Vol. 10, 1–10, 2016
Sunday Ifeanyichukwu Umeh and Peter Anadebe Okonkwo, The Essential Properties of Oils for Biodiesel Production, In Biodiesel Plants – Fueling The Sustainable Outlooks, Intechopen, 2025 DOI:
http://dx.doi.org/10.5772/intechopen.1008694
Otache Monday Abel, Amagbor Stella Chinelo, Inweh Cynthia and Godwin Kparobo Agbajor, Evaluation of African Star Apple (Chrysophyllum albidum) Seed Oil as a Potential Feedstock for Industrial Application, Asian Journal of Applied Chemistry Research, 7(1): 31-42, 2020; Article no.AJACR.57028.
AOAC. Association of official analytical chemists international official methods of analysis. 16th Edition, AOAC, Arlington; 1997.
Mushtaq A, Shazia S, Lee K.T, Ahmed Z.A, Haleema S, Muhammed Z, Taibi B.H, Muhammed A.A, Rasool B.T, Distaff thistle oil: a possible new non-edible feedstock for biogas energy. Int J Green Energy 10:2014, pp.1–27
Egan H, Kirk R.S, Sawyer R, Pearson’s chemical analysis of foods, 8th edn. Churchill Livingstone, London, New York 1981
TutorChase, How do catalysts alter the mechanism of a reaction? Retrieved online June 15,2025 www.tutorchase.com
M. Mathiyazhagan and A. Ganapathi, Factors Affecting Biodiesel Production, Research in Plant Biology,1(2):01-05, 2011 www.resplantbiol.com
I. M. Atadashi, M. K. Aroua, A. R. Abdul Aziz, N.M.N. Sulaiman, The Effects of Catalysts in Biodiesel Production: A Review, journal of industrial and Engineering Chemistry, Vol.19, Issue1, 2013 pp. 14 – 26 https://doi.org/10.1016/j.iec.2012.07.009
SENECA NOTES, Homogeneous catalysts, Retrieved online July 20, 2025. www.senecalearning.com
A. K. Endalew, Y. Kiros, and R. Zanzi, “Heterogeneous catalysis for biodiesel production from Jatropha curcas oil (JCO),” Energy, vol. 36, no. 5, 2011, pp. 2693–2700 Doi:10.1016/j.energy.2011.02.010.
Bello EI Effects of transesterification on the colour of bio diesel. Sci Agric 13: 2016, 10–13
J. I. Orege, O. K. Oderinde, G. A. Kifle, O.O.Ajayi, A.A. Ibikunle, S. A. Raheem, O. Ejeromedoghen, E. S. Okeke, O.M. Olukowi, Recent advances in heterogeneous catalysis for green biodiesel production by transesterification, Energy Convers. Manag., vol. 258(82), 2022 p. 115406 Doi:10.1016/j.enconman.2022.115406.
S. Kumar and R. K. Sani, Eds., Biorefining of Biomass to Biofuels: Opportunities and Perception, vol. 4. in Biofuel and Biorefinery Technologies, vol. 4. Cham: Springer International Publishing, 2018. doi: 10.1007/978-3-319-67678-4.
Prachasanti Thaiyasuit, Kulachate Pianthong , Ittipon Worapun, Acid Esterification- Alkaline Transestrification Process of Methyl Ester Production from Crude Rubber Seed Oil, Journal of Oleo Science 61(2) 2012, pp.81-88
Kartika A, Yani M, Ariono D, Evon PH, Rigal L Biodiesel production from Jatropha seeds: solvent extraction and in situ transesterification in a single step. Fuel 106: 2013, pp.111–117.
A. E. Atabani, A. S. Silitonga, I. A. Badruddin, T. M. I. Mahlia, H. H. Masjuki, and S. Mekhilef, “A comprehensive review on biodiesel as an alternative energy resource and its characteristics,” Renew. Sustain. Energy Rev., vol. 16, no. 4,2012, pp. 2070–2093
Umer R, Farooq A, Gerhard K. Evaluation of biodiesel obtained from cottonseed oil. Fuel Processing Technology. 2009;90: 1157–1163.
Freedman B, Pryde EH, Mounts TL. Variables affecting the yields of fatty esters from transesterified vegetable oils. Journal of American Oil Chemical Society.1984;61:1638- 43.
P. D. Patil and S. Deng, Optimization of Biodiesel Production from Edible and Non-Edible Vegetable Oils, Fuel, 88,2009, pp.1302 – 1306 https://doi.org/10.1016/j.fuel.2009.01.016
F. Ma and M. A. Hanna, Biodiesel Production: A Review, Bioresour. Technol, 70, 1999, pp.1-15
P. Verma and M. P. Sharma, Review of Process Parameters for Biodiesel Production from Different Feedstocks Renewable and Sustainable Energy Reviews, Vol.62,2016, pp.1063-1071 https://doi.org/10.1016/j.rser.2016.04.054
Vegetable Oils and Animal Fats In: Biodiesel. Springer, London. 65–110. DOI:10.1007/978-1-84628-995-8_3
B. B. He, J. C. Thompson, D. W. Routt, J. H. Van Gerpen, Moisture Absorption in Biodiesel and its Petro-Diesel Blends, Applied Engineering in Agriculture, 23(1)2007 Doi: 10.13031/2013.22320
Wikipedia, Pentaclethra macrophylla Retrieved online July 23,2025. https://en.m.wikipedia.org
